1,3-Bis(2-anilino-2-oxoethyl)-1H-imidazol-3-ium chloride acetonitrile monosolvate
نویسندگان
چکیده
In the title compound, C(19)H(19)N(4)O(2) (+)·Cl(-)·C(2)H(3)N, the dihedral angle between the two phenyl rings is 69.57 (8)° while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent mol-ecules into a two-dimensional hydrogen-bonded network parallel to (001); an intra-molecular C-H⋯O hydrogen bond is also observed.
منابع مشابه
1,3-Bis(2-anilino-2-oxoethyl)-1H-imidazol-3-ium chloride dimethylformamide monosolvate
In the imidazolium cation of the title compound, C19H19N4O2(+)·Cl(-)·C3H7NO, the dihedral angles between the imidazole ring and the phenyl rings are 85.86 (4) and 70.26 (5)°. In the crystal, N-H⋯Cl hydrogen bonds link the imdiazo-lium cations and chloride anions into zigzag chains along [110] and together with C-H⋯Cl and C-H⋯O hydrogen bonds, which involve also the dimethyl-formamide solvent mo...
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In the cation of the title salt, C(19)H(19)N(4)O(2) (+)·Cl(-), the dihedral angles between the imidazole ring and the phenyl rings are 70.39 (8) and 86.26 (9)°. The chloride anion inter-acts with the cation through an N-H⋯Cl hydrogen bond. In the crystal, classical N-H⋯O hydrogen bonds link the cations into chains parallel to the b axis. Non-classical C-H⋯Cl and C-H⋯O hydrogen bonds further con...
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